Chemical Analysis Second Edition

Modern Instrumentation Methods and Techniques

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Another, more recent equation, the Knox equation, is applicable to various types of liquid chromatography and includes the adjusted height h:

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Height equivalent to a theoretical plate (HETP)

The equivalent height of a theoretical plate H, as already defined (expression 1.5), is calculated for reference compounds to permit a comp...
Van Deemter’s equation

This equation is based on a Gaussian distribution, similar to that of plate theory. Its simplified form, proposed by Van Deemter in 1956, i...
Injectors

The injector, which is the sample’s entrance to the chromatograph, has different functions. Besides its role as an inlet for the sample, it...
Knox’s equation

Another, more recent equation, the Knox equation, is applicable to various types of liquid chromatography and includes the adjusted height h:
Nernst partition coefficient (K)

The fundamental physico-chemical parameter of chromatography is the equilibrium constant K, termed the partition coefficient, quantifying t...

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